Wow.... this is a great thread... discovered some really great utils..
Here's my list:
Browsers:
IE7
Firefox
Safari (for PC)
PROGRAMS:
Dreamweaver 8 - HTML / CSS
Photoshop CS2 - duh
Swishmax - Flash / SWF
Illustrator CS2 - for importing vector to Swishmax
WS_FTP Pro - FTP
HeidiSQL - Similar to Navicat for MySQL admin
PHP Builder - PHP front end builder for MySQL databases
Easy PHP - explained previously -- awesome tool
Jalbum7.2 - web galleries
3D
Bryce 5