Hello,
I don't use pMA a lot so I can't be sure of this, but if you are using your webhosting company's server, chances are that you do not have "add/edit user" kind of function provided by your host within pMA.
The following is a quote from Main Documentation of phpMyAdmin:
Quote:
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Originally Posted by http://www.phpmyadmin.net/documentation/
NOTE: phpMyAdmin does not apply any special security methods to the MySQL database server. It is still the system administrator's job to grant permissions on the MySQL databases properly. phpMyAdmin's "Privileges" page can be used for this.
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There's also some information regarding the privaleges in pMA in this doc, so if you are interested, you should read it.
Also, if you do not have shell access to your account, then how did you create your first username? If it's a control panel like CPanel, wasn't there any options (privaleges) that you can select upon creating a user?
I think it's best, if you are using a web hosting account, that you ask your hosting provider this question. Maybe they can give you additional username with less privaleges - or at least tell you how to create one.
Hope this helps.